The series of single-side conductive carbon films are made of nano superconducting carbon black, carbon nanotubes and graphene, and then bonded to the substrate by a special pressing process. The composite carbon film prepared by the above process has uniform and stable surface resistance and uniformly bending-resistant material as a whole. Through the packaging process of the later customers, the composite carbon film can be acid-resistant, oil-resistant, heat-resistant, cold-resistant, flame-retardant and oxidation-resistant, and has a service life of more than 20 years. Non-conductive surface has good printing performance, can print a variety of logo patterns according to needs, to meet the personalized LOGO requirements.